화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.10, No.4, 653-660, July, 2004
Preparation of High-Surface-Area Catalysts Supports Coated with SiC by CVI
E-mail:
In this research, permeating dichlorodimethylsilane (DDS) and depositing a Sic layer on surfaces of spherical activated carbons by CVI was studied in a continuous flow reactor. Related mathematical modeling was also undertaken. The results were compared with those obtained in a fluidized bed reactor [1,2]. It is desirable to coat pore walls uniformly with their pore entrances open. The conditions for obtaining these desirable results were a low pressure and a low DDS concentration, such as 10 torr and 3%, respectively. When the deposition rate constant was 10 cm/min, the modeling and experimental results fit well with one another. At a high total pressure and a high partial pressure of DDS, the initial deposition rate was large, but Sic particles deposited at a low pressure were relatively small and uniform. Less uniform deposition was obtained relative to the deposition obtained in a fluidized bed reactor. The dependence of the morphologies of the deposited Sic on both the pressure and concentration were similar to those obtained in a fluidized bed reactor.
  1. Lee SJ, Kim YJ, Kim MH, Rim BO, Chung GY, J. Korean Ind. Eng. Chem., 10(6), 843 (1999)
  2. Lee SJ, Kim MH, Kim YT, Chung GY, Korean J. Chem. Eng., 19(1), 167 (2002)
  3. Juntgen H, Fuel, 65, 1436 (1986)
  4. Laine NR, Vastola FJ, Walker PL, J. Phys. Chem., 67, 2030 (1963)
  5. Murdie N, Hippo EJ, Kowbel W, Proc. Carbon '88, Int. Carbon Conf., 74 (1988)
  6. Vast P, Palavit G, Montagne L, Boulliez JL, Cordier J, Proc. Carbon '88, Int. Carbon Conf., 582 (1988)
  7. Stegenga S, van Wavenren M, Kaptenijn F, Moulijn JA, Carbon, 30, 577 (1992)
  8. Moene R, Tazelaar FW, Makkee M, Moulijn JA, Carbon '94, Proc. 6th Carbon Conf., Granada, Spain, 532 (1994)
  9. Choi W, Lee J, Kim S, Hwang S, Lee MC, Lee TK, J. Ind. Eng. Chem., 9(1), 96 (2003)
  10. Lee GH, Lee MS, Lee GD, Kim YH, Hong SS, J. Ind. Eng. Chem., 8(6), 572 (2002)
  11. Moene R, Makkee M, Moulijn JA, Chem. Eng. J., 53, 13 (1993)
  12. Vannice MA, Chao YL, Friedman RM, Appl. Catal., 20, 91 (1986) 
  13. Camus G, Int. J. Solids Struct., 37, 919 (2000) 
  14. Xu Y, Cheng L, Zhang L, Carbon, 37, 1179 (1999)
  15. Bertrand S, Lavaud JF, Hadi RE, Vignoles G, Pailler R, J. Eur. Ceram. Soc., 18, 857 (1998) 
  16. Zhanga W, Huttinger KJ, Compos. Sci. Technol., 62, 1947 (2002)
  17. Jiang KY, Li HJ, Wang MJ, Mater. Lett., 54, 419 (2002)
  18. Birakayala NY, Evans EA, Carbon, 40, 675 (2002)
  19. Kim K, Choi S, Wang KL, Thin Solid Films, 225 (1993)
  20. Bickerdike RJ, Brown AR, Hughes G, Ranson H, Proc. 5th Conf. on Carbon, Pergamon, New York, Vol. 1 (1992)
  21. Jung SC, Nobuyuki I, Park HC, Proc. Electrochem. Soc., 5, 253 (1996)
  22. Castillo JL, Chem. Eng. Sci., 51, 5325 (1996)
  23. Moene R, Kramer LF, Schoonman J, Maakkee M, Moulijn JA, Scientific Bases for the Preparation of Heterogeneous Catalysts VI, Louvain-la-Neuve, 1, 379 (1994)
  24. Cho MS, Kim JW, Chung GY, Korean J. Chem. Eng., 13(5), 515 (1996)
  25. Chung GY, Cagliostro DE, McCoy BJ, Smith JM, NASA T.M. 103971 (1992)
  26. Chung GY, McCoy BJ, J. Am. Ceram. Soc., 74, 746 (1991)
  27. Chung GY, McCoy BJ, Smith BJ, Cagliostro DE, Chem. Eng. Sci., 47, 311 (1992)
  28. Yamamoto O, Imai K, Sasamoto T, J. Eur. Ceram. Soc., 12, 435 (1993) 
  29. Kikuchi A, J. Ceram. Soc. Jpn., 102, 456 (1994)
  30. Chung GY, McCoy BJ, Smith JM, Gagliostro DE, AIChE J., 39, 1834 (1993)