Journal of Industrial and Engineering Chemistry, Vol.10, No.4, 653-660, July, 2004
Preparation of High-Surface-Area Catalysts Supports Coated with SiC by CVI
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In this research, permeating dichlorodimethylsilane (DDS) and depositing a Sic layer on surfaces of spherical activated carbons by CVI was studied in a continuous flow reactor. Related mathematical modeling was also undertaken. The results were compared with those obtained in a fluidized bed reactor [1,2]. It is desirable to coat pore walls uniformly with their pore entrances open. The conditions for obtaining these desirable results were a low pressure and a low DDS concentration, such as 10 torr and 3%, respectively. When the deposition rate constant was 10 cm/min, the modeling and experimental results fit well with one another. At a high total pressure and a high partial pressure of DDS, the initial deposition rate was large, but Sic particles deposited at a low pressure were relatively small and uniform. Less uniform deposition was obtained relative to the deposition obtained in a fluidized bed reactor. The dependence of the morphologies of the deposited Sic on both the pressure and concentration were similar to those obtained in a fluidized bed reactor.
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