화학공학소재연구정보센터
Journal of the Korean Industrial and Engineering Chemistry, Vol.15, No.4, 434-439, June, 2004
금속처리된 활성탄소를 이용한 축산 분뇨 오염물질의 제거 효율
Removal Efficiency of the Pollutants from Piggery Wastes using Activated Carbon Treated with Metal
E-mail:
초록
금속이 처리된 다층 활성탄을 사용하여 축산 분뇨처리에 관한 연구를 벤치스케일로 수행하였다. Ag+, Cu2+, Na+, K+ 및 Mn2+과 같은 금속이온을 포함하는 수용액에서 처리한 활성탄 시료들의 물리화학적 특성으로써 흡착등온곡선의 형태, 미세동공과 중간동공을 가진 동공 크기분포 등을 연구하였으며, SEM, 그리고 EDX를 통한 표면구조 및 성분분석을 진행하였다. COD, BOD, T-N과 T-P의 제거에 대한 연속적인 촉매효과를 연구하기 위하여, 다층 금속처리 활성탄에 접촉시켜 걸러내었다. 다층 금속활성탄 층을 사용하여 얻어진 오염물질 제거효율이 환경부에서 제시된 기준치 이하의 만족한 결과가 나타났다. 본 연구에서 다층 금속처리된 활성탄의 효율은 유기오염물질의 흡착 및 트랩핑, 촉매적 효과의 결과로서 결정하였다.
The treatment of piggery wastes was carried out, at bench scale, using a multilayered metal-activated carbon system followed by carbon bed filtration. The physicochemical properties were obtained from treated samples with aqueous solutions containing metallic ions: Ag+, Cu2+, Na+, K+ and Mn2+. Isotherm shape and pore distribution with micro and mesopore were examined, and scanning electron microscopy and energy dispersive X-ray were used to inspect the surface structure and composition. Multilayered metal-activated carbons were used for the waste water to investigate the simultaneous catalytic effect on the COD, BOD, T-N, and T-P removal. The results showed a satisfactory removal performance that met the standard of Ministry of Environment of Korea was obtained. Efficiency of the multilayered metal-activated carbon bed was determined by the performance of material for trapping, catalytic effect and adsorption of organic solid particles.
  1. Polaert I, Wilhelm AM, Delmas H, Chem. Eng. Sci., 57(9), 1585 (2002) 
  2. Mckay G, Bino MJ, Water. Air Soil Pollut., 51, 33 (1990) 
  3. Marsh H, Hientz E, Rodriguez-Reinoso EF, Introduction to Carbon Technologies, University of Alicante, Alicante in Spain (1997)
  4. Aksoylu AE, Madalena M, Freitas A, Figueiredo JL, Appl. Catal. A: Gen., 192(1), 29 (2000) 
  5. Hoskins JS, Karanfil T, Serkiz SM, Environ. Sci. Technol., 36, 784 (2002) 
  6. Oh WC, J. Korean Ind. Eng. Chem., 13(5), 434 (2002)
  7. Oh WC, Bae JS, J. Korean Ind. Eng. Chem., 14(1), 29 (2003)
  8. Oh WC, J. Ind. Eng. Chem., 9(2), 117 (2003)
  9. Walker GM, Weatherley LR, Chem. Eng. J., 84(2), 125 (2001) 
  10. Choi KC, Gyoun OA, Kim YD, Kim YH, Lee US, Lee ZY, Chon SJ, Chung SK, Anotation for Standard Methods of Water Quality, Donghwa Technology Publishing Co., 187 (2002)
  11. APHA, Standard Methods for the Examination of Water and Wastewater, 16th Ed. APHA, Washington DC (1982)
  12. Kim JG, Oh WC, Kim MK, J. Korean Ind. Eng. Chem., 9(5), 729 (1998)
  13. Moreno-Castilla C, Carbon, 42, 83 (2004)