화학공학소재연구정보센터
Journal of Chemical Physics, Vol.119, No.20, 10759-10763, 2003
On different possibilities of a thermodynamically consistent determination of the work of critical cluster formation in nucleation theory
In a recent paper [J. Chem. Phys. 118, 1837 (2003)], Kashchiev claimed to have developed a general thermodynamically consistent formula allowing one to describe correctly the work of critical cluster formation in one-component systems for a variety of cases of formation of gaseous, liquid, and solid phases. It is shown that most of the consequences drawn lack any substantiation. (C) 2003 American Institute of Physics.