Carrier doping effect into quasi-one-dimensional bromo-bridged Ni(III) complexes with strong electron-correlation by Cu(II) ions, [Ni1-xCux(chxn)(2)Br]Br2-x

Yamashita M; Ono T; Matsunaga S; Sasaki M; Takaishi S; Iwahori F; Miyasaka H; Sugiura K; Kishida H; Okamoto H; Tanaka H; Hasegawa Y; Marumoto K; Ito H; Kuroda S; Kimura N

Inorganic Chemistry, Vol.42, No.24, 7692-7694, 2003

Yamashita M, Ono T, Matsunaga S, Sasaki M, Takaishi S, Iwahori F, Miyasaka H, Sugiura K, Kishida H, Okamoto H, Tanaka H, Hasegawa Y, Marumoto K, Ito H, Kuroda S, Kimura N

This communication will describe the electron doping effect into Ni-III complexes by Cu-II ions, [Ni1-xCux(chxn)(2)Br]Br2-x (x = 0.038 and 0.101) by using an electrochemical oxidation method. A drastic increase of electrical conductivity as well as a new absorption band around 0.5 eV in single crystal reflectance spectra was observed by doping Cu-II ions, indicating the electron doping was successfully made. An ESR result shows unpaired electrons locate in the d(x2-y2) orbitals of Cu-II and have almost no interaction with those of other ions.