Journal of Vacuum Science & Technology B, Vol.21, No.5, 2026-2028, 2003
Characterization of resistivity and work function of sputtered-TaN film for gate electrode applications
Tantalum nitride (TaN) films were prepared by reactive sputtering in a gas Ar and N-2 for gate electrode applications. Resistivity, crystallinity, and work function of the films were investigated as a function of nitrogen flow rate. As the nitrogen flow rate increased from 0 to 20 sccm, the resistivity of as-deposited TaN films increased from 132 to 1.4 x 10(5) muOmega cm. With a nitrogen flow rate of 8 and 10 sccm, the fcc TaN phase was obtained. The work function of the TaN films was investigated using TaN-gated nmetal-oxide-semiconductor capacitors with SiO2 gate dielectrics of various thicknesses. As the nitrogen flow rate increased from 4 to 12 sccm, the work function decreased from 4.1 to 3.4 eV for as-deposited films. After annealing at 950 degreesC for 1 min, the work function increased to 4.5-4.7 eV, with less dependency on the nitrogen flow rate. (C) 200 American Vacuum Society.