Journal of Physical Chemistry A, Vol.107, No.23, 4588-4591, 2003
Molecular origin of the recognition of chiral odorant by chiral lipid: Interaction of dipahnitoyl phosphatidyl choline and carvone
We present the first effective pair potential (EPP) based theory of recognition of chiral odorant molecule (carvone) by a chiral lipid (dipalmitoyl phosphatidylcholine). The theory explains the experimentally observed preference of the interaction of the lipid with one particular enantiomer of carvone over the other. The theory also reveals interesting discrimination effects, which have significance in the chiral recognition process.