Dye-sensitized solar cells (DSCs) using ionic liquids, 1-alkyl-3-methylimidazolium iodide (alkyl: C-3-C-9), were fabricated with and without a low molecular weight gelator. The highest energy conversion efficiency of 5.0% was obtained from a quasi-solid-state DSC using 1-hexyl-3-methylimidazolium iodide (HMImI). Gelation of these ionic liquids demonstrated better high-temperature durability without decreasing the solar cell efficiency. However, the short-circuit currents (J(SC)) obtained from these DSCs were about 70% of that obtained from DSCs using organic liquid electrolyte (OLE). To explain the difference of the J(SC) values between the DSCs using ionic liquid electrolyte (ILE) and OLE, four primitive processes in DSCs, that is, charge transport in the electrolytes, light absorption by I-3(-), electron diffusion in a TiO2 electrode, and charge recombination, were examined. Viscosities of the ILE decreased with increasing I-3(-) concentration and alkyl chain length. In ILE, measured J(SC) values increased with increasing I-3(-) concentration up to 0.7-1.4 M, depending on the alkyl chain length. Measured J(SC) values showed the same tendency as that estimated using a calculation with a model in which the redox couple is transported by diffusion in electrolytes. These results suggest that the slower diffusion of I-3(-) to the counter electrode (CE) limits the J(SC) values and requires a larger amount of I-3(-) in ILE. However, increasing [I-3(-)] to more than 0.7-1.4 M resulted in the decrease of J(SC). At the optimized concentration of I-3(-) in ILE, the influence of the absorption was estimated to be 13% of the decrease on photocurrent. To the estimate electron diffusion length in the TiO2 electrode, the electron diffusion coefficient (D-e) and electron recombination lifetime (tau) were measured, showing faster De and shorter tau in ILE than in OLE. The faster D-e was caused by the higher concentration of cation in ILE. However, the shorter tau was caused by the higher concentration of I-3(-) and depended on the concentration. Thus, the electron diffusion lengths (L) in the DSC using ILE were shorter than that using OLE. Their shorter L also reduced the J(SC) in the ILE and with the increase of I-3(-) concentration. Among the ILE, the increase of alkyl chain length increased tau. This result should explain the highest efficiency observed in HMImI. During the durability test of the DSC at high temperature, a decrease of the efficiency of the cell using ILE was observed in 1000 h. Time course change of I-3(-) concentration measurements revealed that the gelation of the electrolyte depresses a decrease of I-3(-) concentration caused by sublimation of I-2. Depression of sublimation of I-2 is important to improve the high-temperature durability in nonvolatile ionic liquid electrolyte.