Inorganic Chemistry, Vol.42, No.9, 2836-2838, 2003
Formation and structure of fac-[Mo(CO)(3)(C2H2[N(CH2But)](2)Ge)(3)]: The first structurally characterized group 6 transition metal complex of an unsaturated diaminogermylene
The title compound was obtained from the cyclic diaminogermylene C2H2[N(CH2But)](2)Ge and cis-[Mo(CO)(4)(NCEt)(2)] and its crystal structure determined revealing structural changes in the coordinated ligand indicative of strong pi-acceptor properties.