Zinc Titanate를 이용한 고온건식 탈황반응연구

강석환; 이영우; 강용; 한근희; 이창근; 진경태

HWAHAK KONGHAK, Vol.35, No.5, 642-648, October, 1997

Export Citation

Zinc Titanate를 이용한 고온건식 탈황반응연구

A Study of Desulfurization Reaction using Zinc Titanate at High-Temperature

강석환, 이영우, 강용, 한근희, 이창근, 진경태

초록

ZnO와 TiO₂로 구성된 고온건식 탈황제의 환원, 황화 및 재생반응 특성을 열천칭 반응기에서 수행하였다. TiO₂가 추가된 아연계 탈황제는 ZnO의 환원과 Zn으로의 휘발이 감소하였으며, 탈황제의 사용 온도를 증가시켜 주었다. 650-750 ℃의 온도 범위에서 황화반응의 전환율은 온도에 무관하였지만, 재생반응의 전환율은 비교적 온도의 영향을 받는 것으로 나타났다. 또한 전체적인 반응속도가 물질전달과 표면확산저항에 의해 좌우되는 미반응핵모델을 사용하여 H₂S와 실린더형 탈황제의 반응을 해석하였다. 물질전달계수와 유효확산도의 온도 의존성을 실험결과로부터 얻을 수 있었다.

The reduction, sulfidation and regeneration characteristics of high temperature desulfurization sorbents composed of zinc oxide titanium oxides have been studied in a TGA reactor. The addition of titanium oxides significantly reduced zinc oxide reduction and subsequent volatilization of metallic zinc and increased the maximum sorbent operating temperature. In the temperature range of primary interest(650-750℃) the conversion for the sulfidation reaction was independent of reaction temperatures, while the conversion for regeneration was a relatively weak function of reaction temperature. Also, the reaction between H2S and a single cylindrical pellet of zinc titanate sorbent was described by a special case of the unreacted core model in which the global reaction rate is controlled by mass transfer and product layer diffusion resistances. The temperature dependence of the mass transfer coefficient and the effective diffusivity could be calculated from experimental data.

Keywords:Desulfurization Sorbent;Zinc Titanate;IGCC;TGA

[References]

박태준, 한국전력공사 기술연구원 보고서, 4 (1992)
Phillipson JJ, "Desulfurization in Catalyst Handbook," Wolf, London, England (1970)
Liu CL, Cuang TT, DallaLana IG, Chem. Eng. Sci., 26, 474 (1972)
Westmoreland RR, Harrison DP, Environ. Sci. Technol., 10, 659 (1976)
Lee TJ, Park NK, Kim JH, Kim KS, Park YW, Yi CK, HWAHAK KONGHAK, 34(4), 435 (1996)
Dulin FH, Rase DE, J. Am. Ceram. Soc., 43, 125 (1960)
Gangwal SK, Wood MC, Harrison DP, Groves FR, Jothimurugesan K, In Proceedings of the 8th Annual Gasification and Gas Stream Cleanup Systems Contractor's Review Meeting, ed. Kothari, V.P., Longanbach, J.R., 1, 181 (1988)
Wheast RC, Astle MJ, "CRD Handbook of Chemistry and Physics," CRD Press, Inc., West Palm Beach, Florida (1978)
Perry HR, Chilton CH, "Chemical Engineering's Handbook," 5th Ed., McGrawhill, New York (1973)
Szekely J, Evans JW, Shon HY, "Gas-Solid Reactions," Academic, New York (1976)
Tamhankar SS, Hasatani M, Wen CY, Chem. Eng. Sci., 36, 1181 (1981)
Focht GD, Ranade PV, Herrison DP, Chem. Eng. Sci., 43, 3005 (1988)
강석환, 이영우, 강용, 한근희, 이창근, 진경태, 손재익, 박영성, 에너지공학, 5, 123 (1996)
Tamhankar SS, Garimeiia S, Wen CY, Chem. Eng. Sci., 40, 1019 (1985)
Park DH, Lee YS, Kim HT, Yoo KO, HWAHAK KONGHAK, 30(6), 700 (1992)
Motoo Y, Edward F, Ind. Eng. Chem. Process Des. Dev., 34, 1165 (1985)
Woods MC, Gangwal SK, Jothimurugesan K, Harrison DP, Ind. Eng. Chem. Res., 29, 1160 (1990)
Gupta R, Gangwal SK, "High-Pressure Testing of Zinc Titanate in a Bench-Scale Fluidized-Bed Reactor for 100 Cycles," Topical Report to DOE/METC, June (1993)
이영우, 한근희, 박영성, 손재익, 박영철, 대한환경공학회, 16, 175 (1994)
Westmoreland PR, Gibson JB, Harrison DP, Environ. Sci. Technol., 11(5), 488 (1977)

[Referenced By]

[1] 박태준, 한국전력공사 기술연구원 보고서, 4 (1992)

[2] Phillipson JJ, "Desulfurization in Catalyst Handbook," Wolf, London, England (1970)

[3] Liu CL, Cuang TT, DallaLana IG, Chem. Eng. Sci., 26, 474 (1972)

[4] Westmoreland RR, Harrison DP, Environ. Sci. Technol., 10, 659 (1976)

[5] Lee TJ, Park NK, Kim JH, Kim KS, Park YW, Yi CK, HWAHAK KONGHAK, 34(4), 435 (1996)

[6] Dulin FH, Rase DE, J. Am. Ceram. Soc., 43, 125 (1960)

[7] Gangwal SK, Wood MC, Harrison DP, Groves FR, Jothimurugesan K, In Proceedings of the 8th Annual Gasification and Gas Stream Cleanup Systems Contractor's Review Meeting, ed. Kothari, V.P., Longanbach, J.R., 1, 181 (1988)

[8] Wheast RC, Astle MJ, "CRD Handbook of Chemistry and Physics," CRD Press, Inc., West Palm Beach, Florida (1978)

[9] Perry HR, Chilton CH, "Chemical Engineering's Handbook," 5th Ed., McGrawhill, New York (1973)

[10] Szekely J, Evans JW, Shon HY, "Gas-Solid Reactions," Academic, New York (1976)

[11] Tamhankar SS, Hasatani M, Wen CY, Chem. Eng. Sci., 36, 1181 (1981)

[12] Focht GD, Ranade PV, Herrison DP, Chem. Eng. Sci., 43, 3005 (1988)

[13] 강석환, 이영우, 강용, 한근희, 이창근, 진경태, 손재익, 박영성, 에너지공학, 5, 123 (1996)

[14] Tamhankar SS, Garimeiia S, Wen CY, Chem. Eng. Sci., 40, 1019 (1985)

[15] Park DH, Lee YS, Kim HT, Yoo KO, HWAHAK KONGHAK, 30(6), 700 (1992)

[16] Motoo Y, Edward F, Ind. Eng. Chem. Process Des. Dev., 34, 1165 (1985)

[17] Woods MC, Gangwal SK, Jothimurugesan K, Harrison DP, Ind. Eng. Chem. Res., 29, 1160 (1990)

[18] Gupta R, Gangwal SK, "High-Pressure Testing of Zinc Titanate in a Bench-Scale Fluidized-Bed Reactor for 100 Cycles," Topical Report to DOE/METC, June (1993)

[19] 이영우, 한근희, 박영성, 손재익, 박영철, 대한환경공학회, 16, 175 (1994)

[20] Westmoreland PR, Gibson JB, Harrison DP, Environ. Sci. Technol., 11(5), 488 (1977)