화학공학소재연구정보센터
Journal of Chemical Physics, Vol.118, No.10, 4357-4364, 2003
Quantum dynamics for dissipative systems: A numerical study of the Wigner-Fokker-Planck equation
A study is provided of dynamics and dissipative tunneling in a symmetric quartic double well potential. The numerical solution for the position autocorrelation function obtained through the Wigner-Fokker-Planck equation is compared with numerically exact results of Stockburger and Mak [J. Chem. Phys. 110, 4983 (1999)]. We find that the Wigner-Fokker-Planck dynamics agree well with the numerically exact computations, they account for both quantum coherences as well as quantum tunneling phenomena. This, in contrast to the mixed quantum classical approximation, which does not perform as well. (C) 2003 American Institute of Physics.