화학공학소재연구정보센터
Journal of Applied Polymer Science, Vol.88, No.5, 1336-1345, 2003
Fracture behavior of die-drawn toughened polypropylenes
The Leeds die-drawing process has been used to make oriented sheets of toughened polypropylenes. Die-drawn oriented sheets were produced by drawing at 110degreesC to draw ratios of 4, 6, and 10. Comparative measurements have been undertaken of the plane stress fracture toughness at room temperature using the essential work of fracture method for isotropic and oriented polypropylene homopolymer and the two polypropylene blends containing 10 and 25% of a polyethylene-based elastomer. In the isotropic state, the blend containing 25% elastomer exhibited higher fracture toughness than the homopolymer and the 10% blend. The oriented sheets were tested both parallel (cracks perpendicular to the draw direction) and perpendicular (cracks parallel to the draw direction). For the latter case of cracks parallel to the draw direction, the fracture toughness of all the materials decreased with increasing draw ratio and up to a draw ratio of 4 the 25% blend exhibited higher fracture toughness than the other two materials. At higher draw ratios, however, the unfilled polypropylene was tougher than the blends. When tested parallel to the draw direction, all three materials failed with the cracks growing slowly initially followed by sudden rupture. (C) 2003 Wiley Periodicals, Inc.