화학공학소재연구정보센터
Journal of Chemical Physics, Vol.118, No.4, 2005-2009, 2003
Stokes-Einstein relations and the fluctuation-dissipation theorem in a supercooled colloidal fluid
The Stokes-Einstein (SE) relation is a form of the fluctuation-dissipation theorem (FDT), and relates the diffusion coefficient of colloidal particles to the viscosity via the thermal energy k(B)T. We study the diffusion coefficient and viscosity of concentrated hard-sphere colloidal model systems in the frequency domain. We show that for these metastable fluid systems strong deviations from the SE relation occur, contrary to predictions of mode coupling theory. Using the FDT, these deviations can be quantified by an effective temperature, T-eff. The deviation T-eff/T-1 exhibits power-law behavior over several decades in frequency. (C) 2003 American Institute of Physics.