Industrial & Engineering Chemistry Research, Vol.42, No.1, 50-56, 2003
Emulsion catastrophic inversion from abnormal to normal morphology. 1. Effect of the water-to-oil ratio rate of change on the dynamic inversion frontier
The rate of addition of the internal phase influences the catastrophic inversion of emulsions in the direction of change from abnormal to normal morphology. At a low addition rate, the inversion takes place after a small amount of the internal phase is added, and it happens through the occurrence of multiple emulsion morphology. At a high addition rate, the inversion appears to be delayed, and it takes place without the occurrence of a multiple emulsion.