Journal of Applied Polymer Science, Vol.87, No.4, 641-642, 2003
Relationship between thermodynamical parameters of activated complexes and initial reactants in the reaction of peroxides with amines
The linear dependence between heats of formation and entropies of initial reactants on the one hand and the corresponding thermodynamical parameters of activated complexes on the other hand was obtained for the reaction of peroxides with amines. This relationship allows one to estimate such parameters for other similar reactions of amines with peroxides.