Transmission electron microscopy and the corresponding selected-area electron diffraction patterns of Fe-(10;20;30;40;47) wt. pct. Cr alloys heat treated isothermally from 500degreesC up to 1500degreesC at 100degreesC was employed to construct the equilibrium Fe-rich portion of the Fe-Cr phase diagram. It has been found to be quite different from the generally accepted one. Two regions of phase separation are in the diagram at low and high temperatures. Two lines of the second-order phase transition "ordering-separation" are pointed also. The sigma-phase region in the diagram is considered as a region containing two phases, namely, the sigma-phase surface layer and the solid solution bulk.