Energy Conversion and Management, Vol.43, No.13, 1619-1637, 2002
Thermodynamic analysis of fluids with the possible presence of chemical reactions
Chemically reacting systems with three independent State functions are systematically examined with a mathematical tool with some differences from the Usual one. The thermodynamic relations for the usual fluids depending upon MO State functions are obtained as a Particular case in the absence of the chemical state function. Fluids which obey the relation (V = K(V)f(p/T)). formally similar to Curie's law for magnetic systems, are also investigated. Quasi-static irreversible processes with Uniform intensive properties are considered.
Keywords:Berthelot-De Donder relation;"generalized" Bernoulli equation;systems with (V = K(t)f(p/T));"ordered" and "not ordered" energy;quasi-static irreversible processes