화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.26, No.6, 718-727, November, 2002
Export Citation
Ar(+) 이온 빔 조사가 탄소섬유와 열경화성 수지 간 계면결합력에 미치는 영향
Effects of Ar(+) Ion Beam Irradiation on the Adhesion Forces between Carbon Fibers and Thermosetting Resins
박수진†, 서민강, 김학용1, 이경엽2
  • 한국화학연구원 화학소재연구부
  • 1전북대학교 섬유공학과
  • 2경희대학교 기계ㆍ산업시스템공학부
Soo-Jin Park†, Min-Kang Seo, Hak-Yong Kim1, and Kyong-Yop Rhee2
  • Advanced Materials Division, Korea Research Institute of Chemical Technology, P.O. Box 107, Yusong, Daejon 305-600, Korea
  • 1Dept. of Textile Engineering, Chonbuk Nat'l University, Jeonju 664-14, Korea
  • 2School of Mechanical & Industrial System Engineering, Kyunghee University, Suwon 449-701, Korea
E-mail:
초록
본 연구에서는 최종 복합재료의 기계적 계면특성을 향상시키기 위하여 산소 분위기 하에서 반응성 기체를 사용하는 이온 보조 반응법에 의해 탄소섬유 표면에 Ar(+) 이온 빔을 조사하였다. 그리고, 단일 섬유 pull-out 시험을 실시하여 가해진 이온 에너지 세기에 대한 수지 내의 섬유의 뽑힘 정도를 측정한 후 Greszczuk의 기하학적 모델에 기초하여 섬유/매트릭스 간의 계면특성을 알아보고자 하였다. 그 결과, 탄소섬유를 이온 빔으로 처리함에 따라 섬유와 매트릭스 간의 부착력 증가의 원인이 되는 섬유축 방향으로의 표면 etching 및 반응성 그룹이 형성되어 계면 전단강도가 향상되었으며 0.8 keV 이온 빔 세기에서 최대값을 나타내었다.
In this work, an Ar(+) ion beam was irradiated on carbon fiber surfaces to improve the interfacial shear strength (IFSS) of the resulting composites using an ion assisted reaction (IAR) method. A single fiber pull-out test was executed to investigate the basic characteristics of the single carbon fiber/matrix interface. Based on Greszczuk's geometrical model, the debonding force for pull-out of the fiber from the resins was discussed with the applied ion beam energy. As a result, it was known that an ion beam treatment produced the functional groups on fiber surface and etching lines along the fiber axis direction, resulting in increasing the adhesion forces between fibers and matrix, which caused the improvement of the IFSS in a composite system. And, it was also found that the maximum IFSS was shown at 0.8 keV ion beam energy in this system.
Keywords:interfacial shear strength (IFSS);ion assisted reaction (IAR);single fiber pull-out test;Greszczuk's geometrical model ion beam energy
  1. Wen S, Chung DDL, Cem. Concr. Res., 29, 445 (1999) 
  2. Donnet JB, Bansal RC, "Carbon Fibers," 2ed., Marcel Dekker, New York (1990)
  3. Gregg SJ, Sing KS, "Adsorption Surface Area and Porosity," 2ed., Academic Press, London (1982)
  4. Park SJ, "Interfacial Forces and Fields: Theory and Applications," ed. by J.P. Hsu, Chap. 9, Marcel Dekker, New York (1999)
  5. Melanitis N, Galiotis C, Tetlow PL, Davies CKL, J. Comp. Mater., 26, 574 (1992)
  6. Atkinson KE, Kiley C, Compos. Sci. Technol., 58, 1917 (1998) 
  7. Park SJ, Kim MH, J. Mater. Sci., 35(8), 1901 (2000) 
  8. Weisweiler W, Fitzer E, Nagel G, Jager H, Thin Solid Films, 148, 93 (1987) 
  9. Atkinson KE, Farrow GJ, Jones C, Composites: Part A, 27, 799 (1996) 
  10. Li H, Moshonov A, Muzzy JD, Polym. Compos., 12, 191 (1991) 
  11. Park SJ, Park BJ, Ryu SK, Carbon, 37, 1223 (1999) 
  12. Crane RV, Krukonis VJ, Ceram. Bull., 54, 184 (1974)
  13. Iroh JO, Wood GA, J. Appl. Polym. Sci., 62(10), 1761 (1996) 
  14. Das A, Ghosh G, Dhara S, Patnaik A, Mater. Lett., 38, 82 (1999) 
  15. Guzman L, Celva R, Miotello A, Voltolini E, Ferrari F, Adami M, Surf. Coat. Technol., 104, 375 (1998) 
  16. Dhar NK, Wood CE, Gray A, Wei HY, Salamancariba L, Dinan JH, J. Vac. Sci. Technol. B, 14(3), 2366 (1996) 
  17. Greszczuk LB, "Theoretical Studies of the Mechanics of the Fibre-Matrix Interface in Composites: Interface in Composites," ASTM STP452 (1969)
  18. Barbier B, Ph.D. Thesis, Universit'e Paris 7 (1988)
  19. Zhou LM, Kim JK, Mai YW, Compos. Sci. Technol., 48, 227 (1993) 
  20. Park SJ, Kim JS, Carbon, 39, 2011 (2001) 
  21. Bradley RH, Ling X, Sutherland I, Carbon, 31, 1115 (1993) 
  22. Park SJ, Park BJ, Ryu SK, Carbon, 37, 1223 (1999) 
  23. Drzal LT, Madhukar M, J. Mater. Sci., 28, 569 (1993) 
  24. Sherwood PMA, Mater. Res. Proc., 79, 270 (1992)
  25. Park SJ, Cho MS, Carbon, 38, 1053 (2000) 
  26. Desarmot G, Favre JP, Compos. Sci. Technol., 42, 151 (1991) 
  27. Gray RJ, J. Mater. Sci., 19, 861 (1984) 
  28. Piggott MR, Andison D, J. Reinf. Plast. Comp., 6, 290 (1987)
  29. Chua PS, Piggott MR, Compos. Sci. Technol., 22, 107 (1985) 
  30. Povirk GL, Needleman A, J. Eng. Mater. Technol., 115, 286 (1993)
  31. Penn SL, Lee SM, Fibre Sci. Technol., 17, 91 (1982) 
  32. Lawrence P, J. Mater. Sci., 7, 1 (1972) 
  33. Desarmot G, Sanchez M, "4emes Journees Nat. Comp.," ed. by G.V. Pluralis, p. 449, Paris (1984)
  34. Cox HL, J. Appl. Phys., 3, 72 (1952)
  35. Paiva MC, Bernardo CA, Nardin M, Carbon, 38, 1323 (2000) 
  36. Ramanathan T, Bismarck A, Schulz E, Subramanian K, Compos. Sci. Technol., 61, 599 (2001) 
  37. Park SJ, Kim MH, Lee JR, Choi S, J. Colloid Interface Sci., 228(2), 287 (2000) 
  38. Montes-Moran MA, Martinez-Alonso A, Tascon JMD, Young RJ, Composites: Part A, 32, 361 (2001) 
  39. Hine PJ, Muddarris SE, Packham DE, J. Adhes. Sci. Technol., 69, 1 (1987)