화학공학소재연구정보센터
Chemical Engineering Science, Vol.57, No.12, 2279-2285, 2002
A population balance framework for nucleation, growth, and aggregation
Nucleation, growth, and aggregation for particulate systems are explored by distribution kinetics and population balances to build a new framework for understanding a range of natural and manufacturing phenomena. Nucleation is assumed to follow classical homogeneous theory or to be caused by heterogeneous nuclei added to the solution. Growth due to monomer addition from solution to clusters, and aggregation between clusters are both represented by integrals of the cluster distribution. When growth and aggregation rate coefficients are independent of cluster size, the population balance equations are readily solved by the moment method. Equations for steady-state well-mixed flow and unsteady-state closed (batch) vessels have relatively straightforward solutions. By incorporating solute (monomer) depletion, the results afford reasonable behavior for the cluster number and mass concentration. The monomer addition terms are shown to be consistent with (and a generalization of) conventional differential growth and growth dispersion expressions.