Palmityl 지방족기를 함유하는 제 4급 암모늄염에 의한 PET 섬유의 감량가공 효과

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HWAHAK KONGHAK, Vol.33, No.1, 113-120, February, 1995

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Palmityl 지방족기를 함유하는 제 4급 암모늄염에 의한 PET 섬유의 감량가공 효과

Weight Loss Effects of PET Fibers by Quaternary Ammonium Salts Containing Palmityl Aliphatic Group

박흥수

초록

Palmityldimethylbenzylammonium chloride(PDAC)와 palmityltrimethylammonium methyl sulfate(PTAM)를 합성하고 각각에 물을 가하여 감량촉진제 PDACW와PTAMW를 각각 제조하였다. 제조된 PDACW와 PTAMW 각각을 NaOH와 병용으로 PET 섬유에 감량가공 처리를 한 결과, 감량률은 PTAMW에서 보다 PDACW에서 상당히 컸으며 제 4급 암모늄 염소화물쪽이 제 4급 암모늄 황화물보다 훨씬 양호한 감량효과를 나타내었고, 제 4급 암모늄염의 종류에 따라 감량률은 크게 차이가 생김을 알았다. 이 때 적정 처리농도, 처리시간과 처리액량비는 각각 약 8g/l, 60-90분과 40:1-50:1이었다. 또한 감량촉진제와 PET 섬유와의 반응메카니즘을 고찰하여 감량 촉진제가 촉매로서 거동함을 밝혔다.

PDACW and PTAMW, as a accelerating weight loss agents, were prepared by adding water to palmityldimethylbenzylammonium chloride(PDAC) and palmityltrimethylammonium methyl sulfate(PTAM) synthesized. As a result of weight loss finishing of the PDACW and PTAMW with NaOH on PET fiber, the ratio of weight loss of PDACW was very larger than that of PTAMW. This result showed that quaternary ammonium chloride had higher weight loss effect than quaternary ammonium sulfate, and the ratio of weight loss was greatly varied with the kind of quaternary ammonium salts used. Tn these conditions, proper treatment concentration, treatment time, and treatment bath ratio were about 8g/l, 60-90min, and 40:1-50:1, respectively. From the reaction mechanism of accelerating weight loss agent and PET fiber, acceleration weight loss agent was proved as a catalyst.

[References]

Meredith R, Text. Prog., 7, 1 (1975)
Davis GW, Everage AE, Talbot JR, Fiber Producer, 12, 1 (1984)
Ziabicki A, Kawai H, "High-Speed Fiber Spinning," Wiley-Interscience, New York (1984)
Hashimoto T, Sen-I Gakkaishi, 14, 510 (1958)
Hashimoto T, Sen-I Gakkaishi, 15, 794 (1959)
Kuriyama S, Korematsu M, J. Soc. Fiber Sci. Technol., 16, 110 (1960)
Gawish SM, Bourgeois M, Ambois G, Am. Dyest. Reptr., 74, 36 (1985)
Dave J, Kumar R, Srivastava HC, J. Appl. Polym. Sci., 33, 455 (1987)
Datye KV, Palan BH, J. Appl. Polym. Sci., 38, 1447 (1989)
Kim AS, Kim GJ, J. Korean Fiber Soc., 27, 95 (1990)
Gawish SM, Bourgeois M, Ambroise G, Am. Dyest. Reptr., 73, 37 (1984)
Gawish SM, Bourgeois M, Ambroise G, Am. Dyest. Reptr., 75, 19 (1986)
Park HS, J. Korean Oil Chem. Soc., 10(2), 29 (1993)
Tanaka H, Senshoku Kogyo, 25(7), 350 (1977)
Porter MR, "Handbook of Surfactants," Chapman and Hall, New York (1991)
Shapiro SH, Chefalo T, U.S. Patent, 3,175,008 (1965)
Jungermann E, "Cationic Surfactants," Vol. 4, Marcel Dekker, Inc., New York (1970)
Park HS, J. Ind. Tech. Inst., Coll. Eng., Myong Ji Univ., 11, 81 (1992)
Hummel D, "Identification and Analysis of Surface-Active Agents by Infrared and Chemical Method," John Wiley and Sons, Inc., Sydney (1962)
Fresenius W, Huber JFK, Pungor E, Rechnitz GA, Simon W, West S, "Spectral Data for Structure Determination of Organic Compounds," 2nd ed., Springer-Verlag, Berlin (1989)
Sai IR, Konsei KT, Ryurei SI, "Surfactant Handbook," 18th Ed., Sankyo Tosho Co., Tokyo (1979)
Sanders EM, Zeronian SH, J. Appl. Polym. Sci., 27, 4477 (1982)
Latta BM, Text. Res. J., 54, 766 (1984)
Masuda TR, Shiozawa KO, "Shinhan Sen-I Kako Kishuju," Jijin Shogan Co., Tokyo (1985)
Japan Oil and Fats Co.: "Surfactant Handbook," Kogaku Tosho Co., Tokyo (1987)
Tokiwa F, "Surfactants," Kao Corp., Tokyo (1983)

[Referenced By]

[1] Meredith R, Text. Prog., 7, 1 (1975)

[2] Davis GW, Everage AE, Talbot JR, Fiber Producer, 12, 1 (1984)

[3] Ziabicki A, Kawai H, "High-Speed Fiber Spinning," Wiley-Interscience, New York (1984)

[4] Hashimoto T, Sen-I Gakkaishi, 14, 510 (1958)

[5] Hashimoto T, Sen-I Gakkaishi, 15, 794 (1959)

[6] Kuriyama S, Korematsu M, J. Soc. Fiber Sci. Technol., 16, 110 (1960)

[7] Gawish SM, Bourgeois M, Ambois G, Am. Dyest. Reptr., 74, 36 (1985)

[8] Dave J, Kumar R, Srivastava HC, J. Appl. Polym. Sci., 33, 455 (1987)

[9] Datye KV, Palan BH, J. Appl. Polym. Sci., 38, 1447 (1989)

[10] Kim AS, Kim GJ, J. Korean Fiber Soc., 27, 95 (1990)

[11] Gawish SM, Bourgeois M, Ambroise G, Am. Dyest. Reptr., 73, 37 (1984)

[12] Gawish SM, Bourgeois M, Ambroise G, Am. Dyest. Reptr., 75, 19 (1986)

[13] Park HS, J. Korean Oil Chem. Soc., 10(2), 29 (1993)

[14] Tanaka H, Senshoku Kogyo, 25(7), 350 (1977)

[15] Porter MR, "Handbook of Surfactants," Chapman and Hall, New York (1991)

[16] Shapiro SH, Chefalo T, U.S. Patent, 3,175,008 (1965)

[17] Jungermann E, "Cationic Surfactants," Vol. 4, Marcel Dekker, Inc., New York (1970)

[18] Park HS, J. Ind. Tech. Inst., Coll. Eng., Myong Ji Univ., 11, 81 (1992)

[19] Hummel D, "Identification and Analysis of Surface-Active Agents by Infrared and Chemical Method," John Wiley and Sons, Inc., Sydney (1962)

[20] Fresenius W, Huber JFK, Pungor E, Rechnitz GA, Simon W, West S, "Spectral Data for Structure Determination of Organic Compounds," 2nd ed., Springer-Verlag, Berlin (1989)

[21] Sai IR, Konsei KT, Ryurei SI, "Surfactant Handbook," 18th Ed., Sankyo Tosho Co., Tokyo (1979)

[22] Sanders EM, Zeronian SH, J. Appl. Polym. Sci., 27, 4477 (1982)

[23] Latta BM, Text. Res. J., 54, 766 (1984)

[24] Masuda TR, Shiozawa KO, "Shinhan Sen-I Kako Kishuju," Jijin Shogan Co., Tokyo (1985)

[25] Japan Oil and Fats Co.: "Surfactant Handbook," Kogaku Tosho Co., Tokyo (1987)

[26] Tokiwa F, "Surfactants," Kao Corp., Tokyo (1983)