화학공학소재연구정보센터
Journal of Chemical Physics, Vol.116, No.10, 4054-4057, 2002
Mean excitation energy, static polarizability, and hyperpolarizability of the spherically confined hydrogen atom
Calculations of mean excitation energy, I-m, static polarizability, alpha, and hyperpolarizability, gamma, using the variation perturbation procedure are reported for the spherically confined hydrogen atom. The electric response properties alpha and gamma have been found to strongly depend upon the radius of confinement. The hyperpolarizabilty changes sign and becomes negative under strong confinement.