Molybdenum Di-n-butoxydithiophosphate의 극압 특성

김원덕; 김득기; 정영진; Won Duck Kim; Duk Ki Kim; Yeong Jin Chung

Journal of the Korean Industrial and Engineering Chemistry, Vol.13, No.2, 162-165, April, 2002

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Molybdenum Di-n-butoxydithiophosphate의 극압 특성

Extreme Pressure Characteristics of Molybdenum Di-n-butoxydithiophosphate

김원덕 , 김득기¹, 정영진 ^{2, †}

삼척대학교 신소재공학과, 강원 245-711
¹중앙대학교 화학공학과, 서울 156-756
²삼척대학교 화학과, 강원 245-711

Won Duck Kim , Duk Ki Kim¹, and Yeong Jin Chung^{2, †}

Department of Materials Engineering, Samchok National University, Kangwon 245-711, Korea
¹Department of Chemical Engineering, Chung-Ang Univesrity, Seoul 156-756, Korea
²Division of Chemistry, Samchok National University, Kangwon 245-711, Korea

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초록

용해성 윤활유 첨가제로서 molybdenum di-n-butoxydithiophosphate(MoDTP)의 마모 및 마찰감소에 대하여 시험하였다. Molybdenum di-n-butoxydithiophosphate(MoDTP), zinc di-n-buthyldithiophosphate(ZnDTP), 그리고 MoS2의 현탁용액의 경계윤활 특성 효과를 Timken과 Four-Ball 시험을 통하여 비교한 결과, molybdenum di-n-butoxydithiophosphate 용액의 극압 및 내마모 성질이 다른 것들보다 우수하였다. 또한 MoDTP가 첨가된 윤활유의 동판부식에 대한 산화안정성과 부식방지성 효과가 특히 양호하였다.

Molybdenum di-n-butoxydithiophosphate was investigated as a soluble lubricating oil additive for reducing wear and friction. The boundary lubricating effects of oil solution of molybdenum di-n-butoxydithiophosphate(MoDTP), zinc di-n-buthyldithiophosphate(ZnDTP), and MoS2 supension were compared through Timken and Four-Ball testes. The results showed that the extreme pressure and antiwear properties of the solution of molybdenum di-n-butoxydithiophosphate were superior to those of other additives. Also, the antioxidation and anticorrosion properties for copper strip in oil with added molybdenum di-n-butoxydithiophosphte were found to be especially excellent.

Keywords:extreme pressure;antiwear;antioxidation;molybdenum di-n-butoxydithiophosphate (MoDTP);zinc di-n-buthyldithiophosphate (ZnDTP)

[References]

Hisakado T, Tsukizoe T, Yoshikawa H, Transcations ASME J. Lubrication Technol., 105, 246 (1983)
Liston TV, Tribologist, 40, 280 (1995)
Coy RC, Quinn TEJ, ASLE Trans., 18, 163 (1975)
Yamada Y, Igarashi J, Inoue K, Lubrication Eng., 48(6), 511 (1991)
Satrina HJ, Synthetic Oils and Lubricants Additives, Noyes Data Corporaton, 70 (1982)
Wan Y, Cao L, Xue Q, Tribol. Int., 30(10), 767 (1998)
Rounds FG, ASLE Trans., 24, 431 (1981)
Brit. Patent, 1,016,832 (1963)
Johnson MD, Jensen RK, Korcek S, Soc. Automot. Eng., 37 (1997)
Fish G, Cooper JS, Jisheng E, Davies TD, Isaac RG, PCT Int. Appl. WO 0049, 112 (2000)
Black AL, Dunster RW, Sanders JV, Wear, 13, 119 (1969)
Furniss BS, Hannaford AJ, Smith PWG, Tatchell AR, Textbook of Practical Org. Chem., 400 (1989)
Willermet PA, Mahoney LR, Hass CM, ASLE Trans., 22, 301 (1979)
U.S. Patent, 4,208,292 (1980)
정근우, 석유와 윤활, 여름호, 49 (1998)

[Related Articles]

[1] Hisakado T, Tsukizoe T, Yoshikawa H, Transcations ASME J. Lubrication Technol., 105, 246 (1983)

[2] Liston TV, Tribologist, 40, 280 (1995)

[3] Coy RC, Quinn TEJ, ASLE Trans., 18, 163 (1975)

[4] Yamada Y, Igarashi J, Inoue K, Lubrication Eng., 48(6), 511 (1991)

[5] Satrina HJ, Synthetic Oils and Lubricants Additives, Noyes Data Corporaton, 70 (1982)

[6] Wan Y, Cao L, Xue Q, Tribol. Int., 30(10), 767 (1998)

[7] Rounds FG, ASLE Trans., 24, 431 (1981)

[8] Brit. Patent, 1,016,832 (1963)

[9] Johnson MD, Jensen RK, Korcek S, Soc. Automot. Eng., 37 (1997)

[10] Fish G, Cooper JS, Jisheng E, Davies TD, Isaac RG, PCT Int. Appl. WO 0049, 112 (2000)

[11] Black AL, Dunster RW, Sanders JV, Wear, 13, 119 (1969)

[12] Furniss BS, Hannaford AJ, Smith PWG, Tatchell AR, Textbook of Practical Org. Chem., 400 (1989)

[13] Willermet PA, Mahoney LR, Hass CM, ASLE Trans., 22, 301 (1979)

[14] U.S. Patent, 4,208,292 (1980)

[15] 정근우, 석유와 윤활, 여름호, 49 (1998)