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Journal of Chemical Thermodynamics, Vol.33, No.10, 1215-1226, 2001
(Solid plus liquid) equilibria of (n-alkanes plus ethyl 1,1-dimethylpropyl ether)
(Solid + liquid) equilibria (s.l.e.) have been measured at T > 280 K for (octadecane, or nonadecane, or eicosane, or heneicosane, or docosane, or tricosane, or tetracosane, or hexacosane, or heptacosane, or octacosane + ethyl 1,1-dimethylpropyl ether ETAE). The experimental results are compared with values calculated by means of the Wilson, UNIQUAC and NRTL equations utilizing parameters derived from the experimental s.l.e. The existence of a (solid + solid) first-order phase transition in hydrocarbons has been taken into consideration in the solubility calculations. The solubility of hydrocarbons in branched-chain ethers is lower than that in n-alkanes but higher than that in cycloalkanes, branched alkanes, I-alcohols and tert-alcohols. The best correlation of the solubility data has been obtained by the NRTL equation where the average root-mean-square deviation of the solubility temperatures is 0.36 K.
Keywords:(solid plus liquid) equilibrium;n-alkanes;ethyl 1,1-dimethylpropyl ether ETAE;Wilson;UNIQUAC;NRTL