Journal of Chemical Thermodynamics, Vol.32, No.10, 1327-1334, 2000
Standard molar enthalpies of formation of Ni(CH3COO)(2), Ni(CH3COO)(2)center dot 4.00H(2)O, Cd(CH3COO)(2), and Cd(CH3COO)(2)center dot 2.00H(2)O in the crystalline state
The standard (p(o) = 0.1 MPa) molar enthalpies of formation at the temperature T = 298.15 K of crystalline nickel(II) acetate, Ni(CH3COO)(2), nickel(II) acetate tetrahydrate Ni(CH3COO)(2) . 4.00H(2)O, cadmium(II) acetate Cd(CH3COO)(2), and cadmium(II) acetate dihydrate Cd(CH3COO)(2) . 2.00H(2)O were determined by solution-reaction calorimetry. The enthalpies of dehydration were derived for both complexes. [GRAPHICS]
Keywords:enthalpies of formation;nickel acetate;cadmium acetate;differential scanning calorimetry;solution-reaction calorimetry;enthalpies of dehydration