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Fluid Phase Equilibria, Vol.164, No.2, 157-172, 1999
An effective modification of the Benedict-Webb-Rubin equation of state
A modification of the BWR equation of state is proposed, which is a simplified form of a previously proposed one. It applies to systems formed by hydrocarbons and related compounds, with particular attention to the critical conditions. The range of treatable compounds was extended to a value 0.9 of the acentric factor, corresponding to C-20 hydrocarbons. The critical compressibility factor Z(c) was made independent of the acentric factor, for a more accurate prediction of pure-component properties (the previous equation did not give the same improvement). Mixing rules require one binary interaction constant for each component pair. Zero binary constants can be used for methane-alkane and alkane-alkane pairs. Examples of applications to pure hydrocarbons and their mixtures are given.