Catalysis Today, Vol.46, No.2-3, 155-163, 1998
Formal treatment of catalytic combustion and catalytic conversion of methane
Catalytic combustion and conversion of methane is investigated numerically for transient one-dimensional flow confrgurations (catalytic foil and catalytic wire). The reactive flow is coupled with the processes at the gas-surface interface. The analyses include detailed reaction mechanisms in the gas phase and on the surface as well as a detailed transport model. Computational tools are applied to study the ignition of heterogeneous methane oxidation on a platinum foil and the transition from heterogeneous to homogeneous combustion in this system. Furthermore, the interaction of gas phase and surface reactions in catalytic conversion of methane is considered. Time-dependent selectivity and conversion are calculated.
Keywords:HYDROGEN-AIR;PLATINUM;OXIDATION;IGNITION;EXTINCTION;SIMULATION;MIXTURES;SURFACES;REACTOR;MODEL