CuCl 착화반응을 이용한 파라핀에서부터의 아세틸렌 분리

김동민; 장호남; 송규민; 홍원희

HWAHAK KONGHAK, Vol.31, No.2, 184-192, April, 1993

Export Citation

CuCl 착화반응을 이용한 파라핀에서부터의 아세틸렌 분리

Separation of Acetylene from Paraffins Using CuCl Complex Reaction

김동민, 장호남, 송규민, 홍원희

초록

CuCl 착화반응을 이용하여 파라핀에 포함된 아세틸렌을 분리하는 법을 조사하였다. 착화반응시에는 온도가 낮을수록 혼합이 잘 될 수록 그리고 슬러리에 포함된 CuCl의 양이 많을수록 복합제를 형성하는 아세틸렌의 양이 많았다. 그러나 해리시의 온도가 높거나 슬러리를 연속적으로 사용하면 그 양이 줄어들었다. 슬러리에 CuCl이 포함되지 않거나 착화반응에 적합치 않은 온도에서는 흡수와 물리 흡착만 일어났다.

The separation of acetylene from paraffins using CuCl complex reaction was investigated. The amount of complexed acetylene increased at lower temperature, in better mixing conditions, with the higher amounts of CuCl present in the slurry and at higher dissociation temperatures, but decreased at higher comple-xing temperature and repeated use of slurry. If CuCl is not present or the temperature is not suitable for the complexing reaction, only absorption or physical adsorption of gases can occur.

[References]

Chevastelon CR, Acad. Sci., 126, 1810 (1988)
Berthelot CR, Am. Chem. Phys., 23, 32 (1901)
Gilliland ER, U.S. Patent, 2,209,452 (1940)
Wolk IL, U.S. Patent, 2,386,734 (1945)
Murphree EV, U.S. Patent, 2,515,134 (1950)
Long RB, U.S. Patent, 3,206,521 (1965)
Longwell JP, Long RB, Caruso FA, DeFeo RJ, Walker DG, U.S. Patent, 3,592,865 (1971)
Long RB, U.S. Patent, 3,412,173 (1968)
Komiyama M, Kumira K, Hirai H, Angew. Makromol. Chem., 156, 18 (1988)
Cotton FA, Wilkinson G, "Advanced Inorganic Chemistry," Wiley-Interscience, New York (1972)
Kim DM, M.S. Thesis, KAIST, Seoul (1984)
Gilliland ER, Ind. Eng. Chem., 33, 1143 (1941)
Gilliland ER, J. Am. Chem. Soc., 61, 1960 (1939)
Long RB, Chem. Eng. Symp. Ser., 66, 103 (1970)
Perry RH, Chilton CH, "Chemical Engineers' Handbook," 6th ed., McGraw-Hill, Kogakusha (1973)
National Research Council: "International Critical Tables," McGraw-Hill, New York (1928)
Gilliland ER, J. Am. Chem. Soc., 63, 2088 (1941)
Gray KR, Thurairajan P, Br. Chem. Eng., 13(6), 824 (1968)

[Referenced By]

[1] Chevastelon CR, Acad. Sci., 126, 1810 (1988)

[2] Berthelot CR, Am. Chem. Phys., 23, 32 (1901)

[3] Gilliland ER, U.S. Patent, 2,209,452 (1940)

[4] Wolk IL, U.S. Patent, 2,386,734 (1945)

[5] Murphree EV, U.S. Patent, 2,515,134 (1950)

[6] Long RB, U.S. Patent, 3,206,521 (1965)

[7] Longwell JP, Long RB, Caruso FA, DeFeo RJ, Walker DG, U.S. Patent, 3,592,865 (1971)

[8] Long RB, U.S. Patent, 3,412,173 (1968)

[9] Komiyama M, Kumira K, Hirai H, Angew. Makromol. Chem., 156, 18 (1988)

[10] Cotton FA, Wilkinson G, "Advanced Inorganic Chemistry," Wiley-Interscience, New York (1972)

[11] Kim DM, M.S. Thesis, KAIST, Seoul (1984)

[12] Gilliland ER, Ind. Eng. Chem., 33, 1143 (1941)

[13] Gilliland ER, J. Am. Chem. Soc., 61, 1960 (1939)

[14] Long RB, Chem. Eng. Symp. Ser., 66, 103 (1970)

[15] Perry RH, Chilton CH, "Chemical Engineers' Handbook," 6th ed., McGraw-Hill, Kogakusha (1973)

[16] National Research Council: "International Critical Tables," McGraw-Hill, New York (1928)

[17] Gilliland ER, J. Am. Chem. Soc., 63, 2088 (1941)

[18] Gray KR, Thurairajan P, Br. Chem. Eng., 13(6), 824 (1968)