Journal of Chemical Physics, Vol.107, No.20, 8575-8576, 1997
Fluctuation of the pair-correlation function
Using a simple thermodynamic argument we derive an expression providing the r-dependent fluctuations of the pair-correlation function, g(r), of a liquid. The variance of g(r) at r is a function only of its own value at this point. Fluctuations calculated from Monte Carlo simulations fit well to this formula. (C) 1997 American Institute of Physics. [S0021-9606(97)50244-3].