화학공학소재연구정보센터
Journal of Chemical Physics, Vol.107, No.20, 8397-8408, 1997
The direct observation of electronic coherence in electron transfer reactions possible?
The observability of electronic coherence in electron transfer reactions is discussed. We show that under appropriate circumstances large-amplitude oscillations can be found in the electronic occupation probabilities. The initial preparation of the system is of crucial importance for this effect, and we discuss conditions under which experiments detecting electronic coherence should be feasible. The Feynman-Vernon influence functional formalism is extended to examine more general and experimentally relevant initial preparations. Analytical expressions and path integral quantum dynamics simulations were developed to study the effects of various initial preparations on the observability of electronic coherence. (C) 1997 American Institute of Physics. [S0021-9606(97)02844-4].