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International Journal of Heat and Mass Transfer, Vol.44, No.12, 2379-2382, 2001
Thermodynamically consistent thermal energy equation for an adsorbent/fluid system
We show that thermodynamically inconsistent results art: obtained if a thermal energy equation is used that includes the heat of adsorption in modelling heat and mass transfer of adsorption processes as a surface phenomenon. However, if the heat of adsorption is included in the boundary conditions and not in the thermal energy equation, then the results: are thermodynamically consistent. For a simple example, we found significant differences in temperature changes and heat flux for low Lewis numbers.