The hydrogenation of CO2 was studied over composite catalysts obtained by mixing Cu-based methanol synthesis catalyst and HY zeolite. A mechanism associating methanol synthesis and MTG (methanol to gasoline) reaction allowed the formation of C-1-C-4 hydrocarbons. It was found that the catalytic behaviors of the composite catalysts were favorably influenced by the characteristics of the methanol synthesis catalysts. The Cu-La2Zr2O7 catalyst we recently developed associated with HY zeolite exhibited interesting performances in hydrocarbon synthesis. The addition of ZrO2 to Cu-La2Zr2O7/HY enhanced the ability to produce hydrocarbons. Comparing composite catalyst systems prepared with different Cu-based methanol synthesis catalysts, the effect of Na contamination on methanol and hydrocarbon formation over composite catalysts were also discussed.