공업용 물유리를 이용한 폴리실록산의 합성

강용식; 김원덕

HWAHAK KONGHAK, Vol.30, No.3, 277-284, June, 1992

Export Citation

공업용 물유리를 이용한 폴리실록산의 합성

Synthesis of Polysiloxane from Industrial Water Glass

강용식, 김원덕

초록

공업용 물유리를 황산으로서 silicic acid를 제조하고 제조된 silicic acid를 tetrahydrofuran(THF)으로 추출하여 trimethylchlorosilane(TMCS),dimethyldichlorosilane(DMCS),dichloromethylsilane(DCMS),methyl-trichlorosilane(MTCS)을 각각 반응시켜 생성된 4가지 합성물의 구조와 물성을 조사한 결과 TMCS에서는 선형의 trimethylchlorosilane이 DMDCS애서는 2차원의 dimethylpolysiloxane이 DCMS에서는 H계 2차원 methylpolysi-loxane이 MTCS에서는 3차원 구조의 methylpolysiloxane이 합성되었으며 그리고 이 때 trimethylpolysiloxan은 THF와 CCl₄ 등에 가용이나 dimethylpolysilloxane 혹은 H계 methylpolysiloxane은 난용, methylpolysiloxane은 불용이었다. 가용인 trimethylpolysiloxane의 분자량은 약 13,000이었으며 각 폴리머의 융점은 약 150℃, 분해온도 약 400℃인 무정형 배색 과립상 polysiloxand이 합성됨을 알았다,

The structure and characteristics of the silylates prepared from industrial water glass were stu-died. The structures of the silylates were apparently showed differences by the silylating agents : linear tri-methylpolysiloxane was produced from trimethylchlorosilane, two-dimensional dimethylpolysiloxane from di-methyldilchlorosilane, two-dimensional H-methylpolysiloxane from dichloromethylsilane, and finally three-di-mensional methylpolysiloxane from methyltrichlorosilane. Trimethylpolysiloxane was soluble in tetrahy-drofurane or tetrachlorocarbon, but dimethylpolysiloxane and H-methylpolysiloxane slightly soluble in these solvents, and methylpolysiloxane was not slouble. Each polymer, white amorphous granule has about 13,000molecular weight, about melting point 150℃, and abuot 400℃ decomposition temperature.

[References]

Boer FR, Elynn J, Jurley J, J. Am. Chem. Soc., 90, 6973 (1983)
Perozzi FF, Mortin JC, J. Am. Chem. Soc., 101, 1591 (1979)
Gilman H, Dunn GE, Chem. Rev., 52, 77 (1953)
Ebsworth EVA, "Physical Basis of the Chemistry of the Group IV Elements," in "Organometallic Compounds of the Groups IV Elements," Mac-Diarmid, A.G., Ed., p. 91-104, New York, Marcel Dekker (1968)
Noll W, Angew. Chem.-Int. Edit., 75, 123 (1963)
Wieker W, Hoebbel D, Z. Anorg. Allg. Chem., 336, 139 (1969)
Marsmann MC, Z. Naturforsch, 296, 495 (1974)
Von G, Engelhardt Zeigan D, Jancke H, Hoebbel D, Wieker W, Z. Amorg. Allg. Chem., 418, 17 (1975)
Bardy AB, Brown AG, Huff H, J. Colloid Sci., 8, 256 (1953)
Dent LS, Lachowski EE, Cameron GG, J. Appl. Chem. Biotechnol., 27, 39 (1977)
Alexander GB, J. Am. Chem. Soc., 75, 2887 (1953)
Dent GLS, Doubas N, Smith N, J. Chem. Soc.-Chem. Commun., 727 (1980)
Harris RK, Knight CTG, Smith N, J. Chem. Soc.-Chem. Commun., 726 (1980)
Flemming W, Z. Phys. Chem., 41, 427 (1902)
Hurd CB, Chem. Rev., 22, 403 (1938)
Hurd CB, Pomatti RC, Spittle JH, Alois FJ, J. Am. Chem. Soc., 66, 388 (1944)
Penner SS, J. Polym. Sci., 1, 441 (1946)

[1] Boer FR, Elynn J, Jurley J, J. Am. Chem. Soc., 90, 6973 (1983)

[2] Perozzi FF, Mortin JC, J. Am. Chem. Soc., 101, 1591 (1979)

[3] Gilman H, Dunn GE, Chem. Rev., 52, 77 (1953)

[4] Ebsworth EVA, "Physical Basis of the Chemistry of the Group IV Elements," in "Organometallic Compounds of the Groups IV Elements," Mac-Diarmid, A.G., Ed., p. 91-104, New York, Marcel Dekker (1968)

[5] Noll W, Angew. Chem.-Int. Edit., 75, 123 (1963)

[6] Wieker W, Hoebbel D, Z. Anorg. Allg. Chem., 336, 139 (1969)

[7] Marsmann MC, Z. Naturforsch, 296, 495 (1974)

[8] Von G, Engelhardt Zeigan D, Jancke H, Hoebbel D, Wieker W, Z. Amorg. Allg. Chem., 418, 17 (1975)

[9] Bardy AB, Brown AG, Huff H, J. Colloid Sci., 8, 256 (1953)

[10] Dent LS, Lachowski EE, Cameron GG, J. Appl. Chem. Biotechnol., 27, 39 (1977)

[11] Alexander GB, J. Am. Chem. Soc., 75, 2887 (1953)

[12] Dent GLS, Doubas N, Smith N, J. Chem. Soc.-Chem. Commun., 727 (1980)

[13] Harris RK, Knight CTG, Smith N, J. Chem. Soc.-Chem. Commun., 726 (1980)

[14] Flemming W, Z. Phys. Chem., 41, 427 (1902)

[15] Hurd CB, Chem. Rev., 22, 403 (1938)

[16] Hurd CB, Pomatti RC, Spittle JH, Alois FJ, J. Am. Chem. Soc., 66, 388 (1944)

[17] Penner SS, J. Polym. Sci., 1, 441 (1946)