A carbon-coated graphite is investigated as the negative electrode for Li-ion batteries. The carbon-coated graphite particles are prepared by simple heat-treatment of mixtures, of graphite and poly(vinyl chloride), PVC, at 800-1000 degreesC in an argon flow. The carbon coating reduces significantly the initial irreversible capacity of the graphite in a propylene carbonate-based electrolyte, by suppressing the solvated lithium ion intercalation, and also improves the initial charge-discharge coulombic efficiency. By carbon coating, the specific surface area of graphite particles is greatly increased. These findings can be explained by assuming that a turbostratic structure of PVC-carbon resists irreversible side-reactions which are controlled predominantly by active, edge surface sites.