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Journal of Polymer Science Part B: Polymer Physics, Vol.40, No.3, 290-301, 2002
Unified analysis of thermodynamic and rheological properties of high polymer solutions. I. Binary systems
We present a comprehensive experimental study of thermodynamic and rheological properties of semidilute polymer solutions in good solvent. Osmotic pressure and viscosity measurements have been done in several polymer-solvent systems at different temperatures. A renormalization group technique was applied to analyze the data using de Gennes's blobs model to connect dynamic and conformational quantities. The behavior of polymer systems in the whole range from dilute to semidilute solutions can be satisfactorily described using only a few nonuniversal quantities experimentally determined. An adequate agreement between experiments and theory was found, showing universal behavior with a system-dependent constant beta that does not depend on molecular weight or concentration.