화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.366, 2709-2716, 2001
Phase separation in liquid crystal/gel composites: Role of network elasticity
Phase separation in gets swollen by nematic solvents is investigated using a time-dependent Ginzburg-Landau model. We demonstrate that elasticity of the polymer network is responsible for a foam-like domain morphology observed in polymer dispersed liquid crystals (PDLCs). Rubber elasticity also prevents domain merger, leading to a coarsening behavior substantially slower than in liquid-liquid demixing. We briefly discuss phase separation in nematic polymer gets, in which operates a novel anchoring mechanism mediated by elastic strain.