화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.366, 2505-2512, 2001
Fluctuation-induced Kerr effect near the smectic-A-smectic-C-alpha* phase transition
The anomalous increase of Kerr effect due to pretransitional fluctuations has been investigated in the SmA phase close to the SntA-SmCalpha* transition point in antiferroelectric liquid crystals MHPOBC and MHPOCBC. We have developed a Landau theory taking into account the fluctuations and shown that there are two contributions to the Kerr effect. On the basis of theoretical results. the experimental results obtained in MHPOBC and MHPOCBC were discussed and a clear evidence of the fluctuation-induced Kerr effect was presented.