화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.365, 1611-1619, 2001
Phase diagrams of monomeric and electron beam cured propoxylated glyceroltriacrylate/low molecular weight liquid crystal systems
Equilibrium phase diagrams of mixtures of propoxylated glyceroltriacrylate (GFTA) and low molecular weight liquid crystals (LMWLCs) are investigated. The experimental phase diagrams of monomeric and electron beam (EB) cured GPTA/LMWLC blends are established by polarized optical microscopy (POM). Three LMWLC are used exhibiting different nematic-isotropic transition temperatures. One is the single component LMWLC 4-cyano-4'-n-pentyl-biphenyl (5CB), another one is the eutectic mixture known as E7, and the third one is the single component 4-cyano-4'-n-octyl-biphenyl (8CB) exhibiting both nematic and smectic A orders, The experimental data are successfully analyzed within a unified theoretical treatment based on mean field approximations.