이산화탄소와 Anisole, Methyl anisole 이성질체와의 고압 이성분계 상평형

박상도; 김춘호; 최청송

HWAHAK KONGHAK, Vol.29, No.6, 663-669, December, 1991

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이산화탄소와 Anisole, Methyl anisole 이성질체와의 고압 이성분계 상평형

High Pressure Binary Phase Equilibria of Anisole, Methylanisole Isomers with Carbon Dioxide

박상도, 김춘호, 최청송

초록

상온 상압에서 액상으로 존재하는 방향족 화합물중 anisole과 anisole에 methyl기를 ortho, meta, para 위치에 갖는 2-methylanisole, 3-methylanisole 및 4-methylanisole을 대상으로 이산화탄소의 각각 이성분계를 구성한계에 대해 상태방정식으로 Peng-Robinson(P-R)식과 perturbed-anisotropic-chain theory(PACT) 식을 이용, 평형상수인 K-factor를 이론적으로 구해 실험치와 비교 검토하여 본 계에 적용되는 이들 상태방정식의 특성을 고찰하였다.

Anisole and methyl anisole isomers which containing methyl functional group on anisole at the ortho, meta, para position were chosen as one of the aromatic hydrocarbons and carbon dioxide was chosen as the other component. K-factors obtained by experiment were compared with predictions from the perturb-ed-anisotropic-chain theory(PACT)and the Peng-Robinson(P-R) equation of state. The characteristics of Peng-Robinson(P-R) equation of state and perturbed-anisotropic-chain theory(PACT) which are applied on these systems were investigated.

[References]

Sebastian HM, Nagashwar WD, Lin HM, Chao KC, J. Chem. Eng. Data, 25, 145 (1980)
Morris WO, Donohue MD, J. Chem. Eng. Data, 30, 259 (1985)
Park SD, Kim CH, Choi CS, J. Chem. Eng. Data, 36(1), 80 (1991)
Peng D, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)
Beret S, Prausnitz JM, AIChE J., 21, 1123 (1975)
Vimalchand P, Donohue MD, Ind. Eng. Chem. Fundam., 24, 246 (1985)
Morris WO, Master Thesis, The Johns Hopkins Univ., Baltimore, U.S.A. (1984)
Gubbins KE, Twu CH, Chem. Eng. Sci., 33, 863 (1978)
Carnahan NF, Starling KE, AIChE J., 18, 1184 (1972)
Barker JA, Henderson D, J. Chem. Phys., 47, 474 (1967)
Vimalchand P, Celmins I, Donohue MD, AIChE J., 32, 1735 (1986)
Kim CH, Vimalchand P, Donohue MD, Fluid Phase Equilib., 31, 299 (1986)
Joback KM, M.S. Thesis, Massachusetts Institute of Technology, Mass., U.S.A. (1984)
Reid RC, Prausnitz JM, Poling BE, "The Properties of Gases & Liquids," Fourth Edition, McGraw-Hill Book, Company, New York, NY (1987)
Walsh JM, Jin G, Donohue MD, "Thermodynamics of Short Chain Compounds," Submitted to Fluid Phase Equilibria (1990)
Freeman WH, "Tables of Experimental Dipole Moments," Mcclean, Audrey Lester, San Fransisco (1963)

[Referenced By]

[1] Sebastian HM, Nagashwar WD, Lin HM, Chao KC, J. Chem. Eng. Data, 25, 145 (1980)

[2] Morris WO, Donohue MD, J. Chem. Eng. Data, 30, 259 (1985)

[3] Park SD, Kim CH, Choi CS, J. Chem. Eng. Data, 36(1), 80 (1991)

[4] Peng D, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)

[5] Beret S, Prausnitz JM, AIChE J., 21, 1123 (1975)

[6] Vimalchand P, Donohue MD, Ind. Eng. Chem. Fundam., 24, 246 (1985)

[7] Morris WO, Master Thesis, The Johns Hopkins Univ., Baltimore, U.S.A. (1984)

[8] Gubbins KE, Twu CH, Chem. Eng. Sci., 33, 863 (1978)

[9] Carnahan NF, Starling KE, AIChE J., 18, 1184 (1972)

[10] Barker JA, Henderson D, J. Chem. Phys., 47, 474 (1967)

[11] Vimalchand P, Celmins I, Donohue MD, AIChE J., 32, 1735 (1986)

[12] Kim CH, Vimalchand P, Donohue MD, Fluid Phase Equilib., 31, 299 (1986)

[13] Joback KM, M.S. Thesis, Massachusetts Institute of Technology, Mass., U.S.A. (1984)

[14] Reid RC, Prausnitz JM, Poling BE, "The Properties of Gases & Liquids," Fourth Edition, McGraw-Hill Book, Company, New York, NY (1987)

[15] Walsh JM, Jin G, Donohue MD, "Thermodynamics of Short Chain Compounds," Submitted to Fluid Phase Equilibria (1990)

[16] Freeman WH, "Tables of Experimental Dipole Moments," Mcclean, Audrey Lester, San Fransisco (1963)