First kinetic measurements for CH3O reactions have been obtained for three cyclohydrocarbons using the discharge flow reactor combined with the laser induced fluorescence technique to detect CH3O radicals over the pressure and temperature ranges 1-7 Torr of helium and 300-513 K. Measurements have been performed for the cyclohydrocarbons c-C6H12 (k(1)), c-C6H10 (k(2)), and 1,4-c-C6H8 (k(3)). In addition to the experimental work, we have performed ab initio molecular orbital computations to get an insight into the mechanism of the three reactions, using PMP2, HF-DFT (B3LYP), and CASPT2 methods. The rate constant k(1) has been calculated using the Transition State Theory. Measured rate constants are pressure independent in our experimental range. Arrhenius expressions are (k(1) in cm(3) s(-1)) k(1) = 8.8((-5.0) (+11.0)) x 10(-12) exp[-(24.5 +/- 3.0) Kj mol(-1)/RT] (403-513 K), k(2) (3.1 +/- 0.8) x 10(-12) exp[-(15.3 +/- 0.8) U mol(-1)/RT] (300-503 K), and k(3) = 1.9((+1.6)(-0.9)) x 10(-12) exp[-(7.6 +/- 1.9) Kj mol(-1)/RT] (300-513 K). A good agreement between the experimental -0.9 and theoretical rate constants k(1) has been found. The comparison between the computed and the experimentally determined barrier heights serves as an endorsement of the increasing reactivity in the series from cyclohexane system to the 1,4-cyclohexadiene system.