화학공학소재연구정보센터
Journal of Colloid and Interface Science, Vol.229, No.2, 335-345, 2000
Electrohydrodynamic velocity and pumping measurements in water and alcohols
Bubble and particle velocities in water and alcohols, under the influence of an electric field, were investigated in this work. Air bubbles were injected into the liquids through an electrified metal capillary insulated by glass with its tip left exposed. The end of the capillary from which the bubbles were released was conical in shape. Due to an electric field formed between the noninsulated capillary tip and a ground electrode immersed in the solvent, small bubbles were formed and used as tracers for the electrohydrodynamic (EHD) flow held. The pressure inside the capillary was measured for all liquids used in this study. For water, ethanol, and n-propanol, it was found that, at relatively low applied voltage, the pressure increases with voltage, reaches a maximum (pressure breakpoint), and then sharply decreases. This behavior is a result of the competition between the electric force appearing at the interface and the force due to the Ef-LD flow near the capillary tip. The electric force tends to increase the pressure inside the capillary, while the EHD flow tends to decrease this pressure. For isopropanol and butanol, the pressure breakpoint was not observed in the range of voltage applied in the experiments. The EHD flow velocity was measured by using microbubbles and particles as flow tracers. An adaptive phase-Doppler velocimeter was employed to measure the velocity of bubbles, while the velocity of particles was measured by trajectory visualization of fluorescent particles. A discrepancy was observed between the two methods because of the location at which the measurements were made. It was found that average velocities of both bubbles and particles increase linearly with applied voltage. Experiments were also conducted to investigate pumping of water, which is a result of the EHD velocity near the capillary tip. The pumping flow rate was linearly related to the applied voltage and ag reed well with EHD velocity measurements obtained from particle trajectories.