화학공학소재연구정보센터
Catalysis Letters, Vol.37, No.3-4, 217-221, 1996
A New Synthesis Procedure for Titanium-Containing Zeolites Under Strong Alkaline Conditions and the Catalytic Activity for Partial Oxidation and Photocatalytic Decomposition
A new synthesis procedure for titanium-containing aluminosilicate zeolites has been obtained using a clear colloidal dispersion (sol) which was prepared with titanium isopropoxide, water, hydrochloric acid and colloidal silica, Ludox. When NaY, KL, offretite, mordenite and ZSM-5 zeolites were crystallized from the sol following conventional hydrothermal crystallization procedures, all the aluminosilicate zeolites showed the same X-ray absorption fine structure at the Ti K edge indicating framework Ti. The zeolites showed remarkable catalytic activity for the partial oxidation of cyclohexene using H2O2 as an oxidant and the photocatalytic decomposition of trichloroethene using water.