황산화 폴리아크릴형 내구성 대전방지제에 관한 연구

박홍수; 박대원; 김우재

HWAHAK KONGHAK, Vol.28, No.4, 403-410, August, 1990

Export Citation

황산화 폴리아크릴형 내구성 대전방지제에 관한 연구

Studies on the Durable Antistatic Agent of Sulfated Polyacrylate and Additives

박홍수, 박대원, 김우재

초록

4급화 2-dimethyl aminoethyl methacrylate(DMAC)와 N-methylol acrylamide(MAA)를 공중합시켜 모체수지 poly(DMAC-MAA)를 합성하고, 합성된 용성 공중합체에 높은 흡습성을 가진 lithium chlo-ride와 sodium gluconate를 블렌딩시켜 PET 섬유용 대전방지제를 제조하였다. 제조된 대전방지제를 PET직물에 단독 혹은 수지병용으로 처리한 후 내세탁성 실험결과 낮은 표면저항, 적은 값의 미찰대전압 및 짧은 감쇄 반감기 값을 가지는 양호한 대전방지제임이 입증되었다.

Base resin of poly(DMA-MAA) copolymer was synthesized by copolymerizing N-methylol acryl-amide(MAA) with quaternized 2-dimethyl aminoethyl methacrylate(DMAC). Antistatic agent treating to PET woven fabrics was prepared by blending water soluble poly(DMA- MAA)with lithium chloride and sodium gluconate having high hydroscopic properties. Treating with and without resin to PET textile and washing tests revealed that the syn-thesized antistatic agents were good durable ones having low surface resistance, small frictional voltage and short decay half time of electric charge.

[References]

Helmholtz H, J. Am. Phys., 7, 337 (1879)
Coehn A, J. Wred. Ann., 64, 217 (1898)
Hersh SP, Montgomery DJ, Text. Res. J., 25, 61 (1955)
Gonsalves VE, van Dongeren BJ, Text. Res. J., 24, 1 (1954)
Hersh SP, Sharman EP, Text. Res. J., 24, 426 (1954)
Cunnigham RG, Montgomery DJ, Text. Res. J., 18, 971 (1958)
Sugiyama SZ, Surface, 21, 36 (1983)
Henshall AE, J. Soc. Dyers Color, 76, 525 (1960)
Marumo H, Takai M, Saito M, Kogyo Kag Zasshi, 72, 940 (1969)
Wilson N, Text. Inst. Ind., 10, 235 (1972)
Mizutani T, Mitani K, Ieda M, Jpn. J. Appl. Phys., 22(4), 677 (1983)
Lewis DM, Text. Res. J., 54(5), 279 (1984)
Vigo TL, Bruno JS, J. Appl. Polym. Sci., 37(2), 371 (1989)
Tambor M, Cope JL, Jerome JL, U.S. Patent, 4,737,156 (1988)
Maity NC, Kartha KPR, Srivastava HC, Colourage, 31(24), 11 (1984)
Wilson N, Text. J. Austr., 51(7), 10 (1976)
Kimura Y, Angew. Makromol. Chem., 132, 169 (1985)
Ona I, Ozaki M, Japan Kokai 88, 23, 976 (1988)
Kyou Wa Gas Co.: Japan Kokai 86, 40, 258 (1986)
Ganmo S, Kogyo Kag. Zasshi, 69, 1504 (1966)
Rath H, herbolsheimer E, Stapt S, Text. Res. J., 30, 201 (1960)
Marsh JT, "An Introduction to Textile Finishing," 1st ed., p. 247, Chapman & Hall Ltd., New York (1950)
Venkatesh GM, Das TK, Pal S, Atira Tech. Dig., 13(2), 4 (1979)
Holmes FH, Heap SA, J. Soc. Dyers Color., 83, 12 (1967)
Ganmo S, Kogyo Kag. Zasshi, 72, 940 (1969)

[Referenced By]

[1] Helmholtz H, J. Am. Phys., 7, 337 (1879)

[2] Coehn A, J. Wred. Ann., 64, 217 (1898)

[3] Hersh SP, Montgomery DJ, Text. Res. J., 25, 61 (1955)

[4] Gonsalves VE, van Dongeren BJ, Text. Res. J., 24, 1 (1954)

[5] Hersh SP, Sharman EP, Text. Res. J., 24, 426 (1954)

[6] Cunnigham RG, Montgomery DJ, Text. Res. J., 18, 971 (1958)

[7] Sugiyama SZ, Surface, 21, 36 (1983)

[8] Henshall AE, J. Soc. Dyers Color, 76, 525 (1960)

[9] Marumo H, Takai M, Saito M, Kogyo Kag Zasshi, 72, 940 (1969)

[10] Wilson N, Text. Inst. Ind., 10, 235 (1972)

[11] Mizutani T, Mitani K, Ieda M, Jpn. J. Appl. Phys., 22(4), 677 (1983)

[12] Lewis DM, Text. Res. J., 54(5), 279 (1984)

[13] Vigo TL, Bruno JS, J. Appl. Polym. Sci., 37(2), 371 (1989)

[14] Tambor M, Cope JL, Jerome JL, U.S. Patent, 4,737,156 (1988)

[15] Maity NC, Kartha KPR, Srivastava HC, Colourage, 31(24), 11 (1984)

[16] Wilson N, Text. J. Austr., 51(7), 10 (1976)

[17] Kimura Y, Angew. Makromol. Chem., 132, 169 (1985)

[18] Ona I, Ozaki M, Japan Kokai 88, 23, 976 (1988)

[19] Kyou Wa Gas Co.: Japan Kokai 86, 40, 258 (1986)

[20] Ganmo S, Kogyo Kag. Zasshi, 69, 1504 (1966)

[21] Rath H, herbolsheimer E, Stapt S, Text. Res. J., 30, 201 (1960)

[22] Marsh JT, "An Introduction to Textile Finishing," 1st ed., p. 247, Chapman & Hall Ltd., New York (1950)

[23] Venkatesh GM, Das TK, Pal S, Atira Tech. Dig., 13(2), 4 (1979)

[24] Holmes FH, Heap SA, J. Soc. Dyers Color., 83, 12 (1967)

[25] Ganmo S, Kogyo Kag. Zasshi, 72, 940 (1969)