화학공학소재연구정보센터
Journal of Physical Chemistry B, Vol.103, No.35, 7514-7521, 1999
A new exact method for solving the two-dimensional Ising model
We have used the two-dimensional Ising model with a limited number of rows, but with the coordination number of four for each site, to set up the transfer matrix for the model. From the solution of such a matrix, the exact thermodynamic properties have been obtained for the model with a definite number of rows, n. We have solved the matrix for n less than or equal to 7 and n less than or equal to 10 in the presence and absence of a magnetic field, respectively. On the basis of such solutions, we have proposed an analytical expression for the partition function of the model with any number of rows in the absence of a magnetic field. The proposed expression becomes more accurate when n is larger, in such a way that it becomes very accurate for n greater than or equal to 8 and is exact for n -->infinity. Our results show that the singularity of the specific heat occurs only for the model with infinite number of rows. In the presence of a magnetic field, the solution to the matrixes is too complicated to propose a general analytical expression for the partition function of the model with any number of rows. However, our exact solution for the model with n = 4, 5, 6, and 7 reveals an important point that such results are independent of n when the field-spin interaction energy is almost equal to or larger than that of the spin-spin interaction.