화학공학소재연구정보센터
Journal of Physical Chemistry B, Vol.103, No.28, 5743-5746, 1999
Origin of photovoltage and photocurrent in the nanoporous dye-sensitized electrochemical solar cell
The essential role of the dark equilibrium potential is discussed for charge separation and the photovoltaic functioning of the title cell. A quantitative model is presented for the potential distribution in the sponge-type title cell. The unique screening process for the photogenerated electrons is discussed that facilitates their extremely long lifetime since the screening ions cannot function as recombination centers. A general analogy is pointed out for the photovoltaic functioning of the sponge-type electrochemical solar cell and of a conventional single-crystal solid-state solar cell.