Journal of Physical Chemistry A, Vol.103, No.48, 9712-9716, 1999
Electronic spectra of the carbon chain anions C2n-1-H-1(-) (n=5-8) in the gas phase
The electronic absorption spectra of the monohydrogenated odd carbon chain anions C2n-1H- (n = 5-8) have been measured in the gas phase using resonant two-color electron detachment spectroscopy. As for the even series C2nH- (n = 5-10) electronic transitions of two isomeric species are observed. Ab initio calculations on C9H- support the assignment of one band system to a (3)Sigma(-) <-- X(3)Sigma(-) transition of a linear molecule and the other Co a (1)A' <-- X(1)A' transition of a bent isomer. The wavelength of the band systems shows an approximately linear dependence on the chain length. This plot is offset by 60 nm compared to the one for the linear C2nH-anions, while the wavelengths for the even and odd carbon series of the cumulene-like isomer fall on the same line. These trends can be rationalized in terms of their electronic structure.