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Canadian Journal of Chemical Engineering, Vol.74, No.6, 1034-1038, 1996
Coking Kinetics of a Cr2O3/Al2O3 Catalyst During 1-Butene Dehydrogenation - Effect of H-2 Partial-Pressure
The influence has been studied of the partial pressure of hydrogen (0-30 kPa) upon the coking rate of a Cr2O3/Al2O3 commercial catalyst during 1-butene dehydrogenation. Coke deposition has been analysed using a monolayer-multilayer reversible coke growth model (MMRC model). This model provides good fits to the experimental data, within the range of partial pressure of H-2 studied, and allows us to estimate the main kinetic parameters involved in the coking-deactivation process. The results obtained reveal a dual effect of hydrogen : competition against 1-butene for the active sites and the removal of coke precursors from the catalyst surface. Both effects diminish the coking rate as the H-2, partial pressure is increased.