In this work, the relationships between composition and properties of Ny6/EVOH system were examined by means of several techniques and the results were interpreted in terms of level of compatibility. Blends of different ration of Ny6 and EVOH have been processed in a laboratory-based film blowing extrusion apparatus. Rheological measurements, FTIR and morphological analysis, and thermal and mechanical properties were carried out. Peculiar rheological, thermal, and mechanical behaviors were observed for the blend containing 25% by weight of EVOH. At this composition, FTIR analysis has pointed out that a minimum in molecular motion is achieved as a consequence of a maximum interaction of the polar groups (amide group if Ny6 and hydroxyl groups of EVOH) involved. Moreover, gas permeability measurements on the blown films have been performed at T = 30 degrees C.