4-(N,N-Diallylamino)pyridine (DAAP), N,N-diallylaminobenzene (DAAB), N,N,N',N'-tetrallyl-4,4'-diaminobenzidine (AAB), N,N,N',N'-tetrallyl-4,4'-diaminodiphenyl sulfone (AABS), and N,N,N',N'-tetrallyl-4,4'-diaminodiphenyl ether (AABE) were prepared by sodium substitution and N-allylation. Moreover, linear polyDAAP, poly(DAAP-co-DAAB), and network poly(DAAP-co-AAB), poly(DAAP-co-AABS), and poly(DAAP-co-AABE), all being polymers containing supernucleophilic groups, were synthesized in the cyclopolymerization.