화학공학소재연구정보센터
Journal of the Electrochemical Society, Vol.147, No.11, 4345-4350, 2000
Catalytic methane sensor using a Ni-CaZr0.9In0.1O3-alpha cermet electrode
A catalytic asymmetrical Nernst-type methane sensor with a porous Ni-CaZr0.9In0.1O3-alpha, Cermet electrode has been developed. At 600 and 700 degreesC a Nernst-like behavior of the sensor is observed as a function of the methane partial pressure with a slope of 56 and 26 mV/decade, respectively. At 500 degreesC a deviation from this behavior is found. The temperature dependence of the sensor response can be explained by the difference in catalytic activity of nickel and platinum. The sensor response depends on the CO2 concentration, but it is shown that the measured electromotive force can be corrected for the CO2 concentration in the gas mixture. The presence of water in the gas mixture leads to a decrease of the sensitivity, which can be explained by the different catalytic response of nickel and platinum to the presence of water. The sensor shows good reproducibility and long-term stability. The effect of the gas flow rate on the sensor performance is found to be minimal.