Thr performance of a single-chamber solid oxide fuel cell (SOFC) was studied between 350 and 900 degrees C in flowing mixtures of methane, ethane, propane, or liquefied petroleum gas and air with a fuel/air volume ratio of one, where their oxidation proceeded safely without explosion. Among all tested electrode materials, Ni-Ce0.8Sm0.2O1.9 cermet and Sm0.5Sr0.5CoO3 oxide functioned best as the anode and cathode, respectively, in various gas mixtures. A cell constructed from a La0.9Sr0.1Ga0.8Mg0.2O3 electrolyte with the two electrodes generated >900 mV in a methane-air mixture between 600 and 800 degrees C and in an ethane-air mixture between 450 and 650 degrees C. A small electrode reaction resistance resulted in increasing power density with decreasing electrolyte thickness. The peal, power density at 450 degrees C increased from 34 to 101 mW cm(-2) with decreasing electrolyte thickness from 0.50 to 0.18 mm. The working mechanism of the single-chamber SOFC at different temperatures was also studied by measuring the catalytic activities of the two electrodes for partial oxidation of the hydrocarbons.