수용성 4-알킬-3-술폰화된 호박산 염류의 계면성

김명수; 정환경; 박홍조; 남기대; Myeong Soo Kim; Kwan Kyeong Jeong; Heung Cho Park; Ki Dae Nam

Journal of the Korean Industrial and Engineering Chemistry, Vol.12, No.4, 461-466, June, 2001

Export Citation

수용성 4-알킬-3-술폰화된 호박산 염류의 계면성

Surface Active Properties of the Disodium 4-n-Alkyl-3-Sulfonatosuccinate in Aqueous Solution

김명수 , 정환경¹, 박홍조², 남기대^†

충북대학교 화공학보 공업화학, 청주 361-763
¹삼성전자 천안 반도체 AMLCD, 천안 330-300
²충주대학교 고분자공학과, 충주 380-702

Myeong Soo Kim , Kwan Kyeong Jeong¹, Heung Cho Park², and Ki Dae Nam^†

School of Chemical Engineering, Chungbuk National University, Cheongju 361-763, Korea
¹AMLCD Division Semiconductor, Samsung Electronics, Chunan 330-300, Korea
²Department of Polymer Engineering, Cheongju National University, Cheongju 380-702, Korea

E-mail:

초록

Disodium 4-n-alkyl-3-sulfonatosuccinate와 같이 헤드그룹이 두 개이고 소수성부인 탄화수소의 탄소수가 8 ~ 12범위인 음이온성 계면활성제의 미셀형성 특이성이 형광법, 자외선 스펙트럼 및 산-염기 적정법으로 실험 검토되었고, 미셀 내부의 활성은 pyrene과 8-anilino-1-naphthalene sulfoam-monium salt로 비교검토되고, pyrene I1/I3 비율이 미셀 주위에 층이 둘러싸여진 미소 환경을 검토하는데 사용되었다. 두 개의 이온성 헤드그룹에 대한 pK3 값은 산-염기적정으로 측정되었고, 표면전위량은 미셀 계면에서 소수성 반응지시약인 7-hydroxycoumarine의 pK(a) 값에서 산출되었다.

The micellar properties of two-headed surfactants, disodium 4-n-alkyl-3-sulfonatosuccinates, s a function of alkyl chain length (C8 ~ C12) of anionic surfactants were investigated by employing fluorescence, ultra-violet spectroscopy, and acid-base titration methods. Polarity of the micellar's interior was studied using pyrene and 8-anilino-1-naphthalene sulfoammonium salt. Pyrene of I1/I3 ratio was used to investigate the microenvironment of palisade layer of the micelle. The pK(a) vlues for both of the anionic bead groups were determined using acid-base titrations. The surface potentials were obtained from meaurement of the pK(a) of hydrophobic indicator, 7-hydroxycoumarin, at the interface of sulfonatosuccinate micellar.

Keywords:two-headed surfactant;pyrene;microenvironment;micellar interior

[References]

Boucher GD, Hawrylak B, MacDonald A, Margoni DG, Can. J. Chem., 76, 1266 (1998)
Comeau EK, Beck EJ, Caplon JK, Howley CV, Margoni DG, Can. J. Chem., 73, 1741 (1995)
Jobe DJ, Reinsburough VC, Aust. J. Chem., 37, 303 (1984)
Hartland GV, Grieser F, White LR, J. Chem. Soc.-Faraday Trans., 83, 591 (1987)
Drummond CJ, Grieser F, J. Phys. Chem., 92, 5589 (1988)
Drummond CJ, Grieser F, Photochem. Photobiol., 45, 19 (1987)
Grieser F, Drummond CJ, J. Phys. Chem., 92, 5580 (1988)
Caryl CR, Ind. Eng. Chem., 33, 741 (1941)
Hoffmann H, J. Soc. Cosmet. Chem., 591 (1963)
West RC, "CRC Handbook of Chemistry and Physics", 70th ed., CRC Press. Boca Raton. Fla (1990)
Mukerjee P, Banerjee K, J. Phys. Chem., 68, 3567 (1964)
Grieser F, Drummond CJ, Warr GG, Ninham BW, Evans D, J. Phys. Chem., 89, 2103 (1985)
Kibblewhite J, Drummond CJ, Grieser F, Healy TH, J. Phys. Chem., 91, 4658 (1987)
Drummond CJ, Grieser F, Healy TH, J. Phys. Chem., 92, 2064 (1988)
Carners RC, Colloid Polym. Sci., 273, 1033 (1995)
Bhattacharyya K, Chowdhury M, Chem. Res., 93, 507 (1993)
Karpovich DS, Blanchard GJ, J. Phys. Chem., 99(12), 3951 (1995)
Dong DC, Winnick MA, Can. J. Chem., 62, 2560 (1984)
William EF, Woodberry NT, Dixon JK, J. Colloid Sci., 12, 452 (1957)
Lovelock B, Grieser F, Healy TH, J. Phys. Chem., 89, 501 (1985)
Tanford C, "The hydrophobic effect", Wiley, New York, 42 (1980)
Ganesh KN, Mitra P, Balasubramanian D, J. Phys. Chem., 86, 279 (1982)

[Related Articles]

[1] Boucher GD, Hawrylak B, MacDonald A, Margoni DG, Can. J. Chem., 76, 1266 (1998)

[2] Comeau EK, Beck EJ, Caplon JK, Howley CV, Margoni DG, Can. J. Chem., 73, 1741 (1995)

[3] Jobe DJ, Reinsburough VC, Aust. J. Chem., 37, 303 (1984)

[4] Hartland GV, Grieser F, White LR, J. Chem. Soc.-Faraday Trans., 83, 591 (1987)

[5] Drummond CJ, Grieser F, J. Phys. Chem., 92, 5589 (1988)

[6] Drummond CJ, Grieser F, Photochem. Photobiol., 45, 19 (1987)

[7] Grieser F, Drummond CJ, J. Phys. Chem., 92, 5580 (1988)

[8] Caryl CR, Ind. Eng. Chem., 33, 741 (1941)

[9] Hoffmann H, J. Soc. Cosmet. Chem., 591 (1963)

[10] West RC, "CRC Handbook of Chemistry and Physics", 70th ed., CRC Press. Boca Raton. Fla (1990)

[11] Mukerjee P, Banerjee K, J. Phys. Chem., 68, 3567 (1964)

[12] Grieser F, Drummond CJ, Warr GG, Ninham BW, Evans D, J. Phys. Chem., 89, 2103 (1985)

[13] Kibblewhite J, Drummond CJ, Grieser F, Healy TH, J. Phys. Chem., 91, 4658 (1987)

[14] Drummond CJ, Grieser F, Healy TH, J. Phys. Chem., 92, 2064 (1988)

[15] Carners RC, Colloid Polym. Sci., 273, 1033 (1995)

[16] Bhattacharyya K, Chowdhury M, Chem. Res., 93, 507 (1993)

[17] Karpovich DS, Blanchard GJ, J. Phys. Chem., 99(12), 3951 (1995)

[18] Dong DC, Winnick MA, Can. J. Chem., 62, 2560 (1984)

[19] William EF, Woodberry NT, Dixon JK, J. Colloid Sci., 12, 452 (1957)

[20] Lovelock B, Grieser F, Healy TH, J. Phys. Chem., 89, 501 (1985)

[21] Tanford C, "The hydrophobic effect", Wiley, New York, 42 (1980)

[22] Ganesh KN, Mitra P, Balasubramanian D, J. Phys. Chem., 86, 279 (1982)